Rule bt0268
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1-MethylcarboxylCoA -> 1-MethylenecarboxylCoA
| Aerobic Likelihood: | | Unlikely |
EAWAG-BBD Reaction(s):
Pivalyl-CoA -----> 3-Methylbutyryl-CoA (reacID# r1033)
Comments:
Carbon chain rearrangement; the 2 carbon can have H, methyl or carboxylate substituents. Based on methylmalonyl-CoA mutase EC 5.4.99.2 and isobutyryl-CoA mutase EC 5.4.99.13 (see Figure 1 of Ratnatilleke et al., 1999). CoA ligation to the terminal carboxyl group occurs prior to the reaction but is bypassed in this rule for simplification.
Similarities:
bt0312: 1-MethylenecarboxylCoA --> 1-MethylcarboxylCoA
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Page Author(s):
Dave Roe and Michael Turnbull
January 30, 2009
This is the EAWAG-BBD biotransformation rule, ruleID# bt0268.
It was generated on February 8, 2025 1:43:10 AM CST.
© 2025, EAWAG.
