Rule bt0312

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Pattern 3818
1-MethylenecarboxylCoA -> 1-MethylcarboxylCoA

Aerobic Likelihood:              Unlikely

EAWAG-BBD Reaction(s):
(1-Methylpentyl)succinyl-CoA -----> (2-Methylhexyl)malonyl-CoA (reacID# r0922)

Carbon chain rearrangement; the 2 carbon can have H, methyl or carboxylate substituents. Based on methylmalonyl-CoA mutase EC and isobutyryl-CoA mutase EC (see Figure 1 of Ratnatilleke et al., 1999). CoA ligation to the terminal carboxyl group occurs prior to the reaction but is bypassed in this rule for simplification.

bt0268: 1-MethylcarboxylCoA --> 1-MethylenecarboxylCoA

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Page Author(s): Dave Roe, Michael Turnbull
November 20, 2008

This is the EAWAG-BBD biotransformation rule, ruleID# bt0312.
It was generated on September 20, 2017 8:32:42 PM CDT.

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