From 2,5-Diketocamphane to 2-Oxo-delta3-4,5,5-trimethylcyclopentenylacetate

Graphic of the reaction.

Medline reference
Jones KH, Smith RT, Trudgill PW. J Gen Microbiol (1993) 139(4): 797-805.

Search Medline for 2,5-diketocamphane 1,2-monooxygenase.
6 citations on October 11, 2012. 
                 2,5-Diketocamphane                  
                          |
                          |  NADH + H+ + O2
       2,5-diketocamphane | /
        1,2-monooxygenase |/
              1.14.13.162 |
                    Kyoto |\
                   ExPASy | \
                          |  NAD+ + H2O
                          v
               [5-Oxo-1,2-campholide]                
                          |
                          |
                          |
                          |
                          |
                          |
                          |
                          v
  2-Oxo-delta3-4,5,5-trimethylcyclopentenylacetate
Display a pathway starting from this reaction.

EAWAG-BBD Biotransformation rules in accord with this reaction:
cyclic Ketone -----> cyclic Ester (bt0071)
5-Oxo-1,2-campholide -----> 2-Oxo-4,5,5-trimethylcyclopenenylacetate derivative (bt0271)
[(+)-Camphor] [BBD Main Menu]

Page Author(s): Dong Jun Oh
August 14, 2005 Contact Us

This is the EAWAG-BBD reaction, reacID# r0428.
It was generated on November 12, 2025 at 2:38:09 PM CST. 

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