Rule bt0071

[Pathway Prediction Engine] [All Rules List] [BBD Main Menu]

Pattern 4150
cyclic Ketone -> cyclic Ester


Aerobic Likelihood:              Neutral

EAWAG-BBD Reaction(s):
Adamantanone -----> 4-Oxahomoadamantan-5-one (reacID# r0681)
Cyclohexanone -----> 1-Oxa-2-oxocycloheptane (reacID# r0166)
2,5-Diketocamphane -----> 2-Oxo-delta3-4,5,5-trimethylcyclopentenylacetate (reacID# r0428)
(1S,4R)-1-Hydroxy-2-oxolimonene -----> (3R)-3-Isopropenyl-6-oxoheptanoate (reacID# r0736)
5-Hydroxyadamantan-2-one -----> 1-Hydroxy-4-oxahomoadamantan-5-one (reacID# r0682)
1-Indanone -----> 3,4-Dihydrocoumarin (reacID# r0417)
2-Indanone -----> 3-Isochromanone (reacID# r0424)
2-Oxo-delta3-4,5,5-trimethylcyclopentenylacetyl-CoA -----> delta2,5-3,4,4-Trimethylpimelyl-CoA (reacID# r0430)

Comments:
Baeyer-Villiger oxidation of saturated rings. Based on M. D. Mihovilovic (2006) Curr Org Chem 10:1265-1287.

Similarities:
bt0423: Acetophenone derivative --> Acetylphenol derivative

Contact Us if you have any comments on rule bt0071.
[Pathway Prediction Engine] [All Rules List] [BBD Main Menu]

Page Author(s): Bo Kyeng Hou, Michael Turnbull and Jiun-guo Yu
April 30, 2009

This is the EAWAG-BBD biotransformation rule, ruleID# bt0071.
It was generated on September 25, 2017 4:42:36 AM CDT.

© 2017, EAWAG.