From (1S,4R)-1-Hydroxy-2-oxolimonene to (3R)-3-Isopropenyl-6-oxoheptanoate

Graphic of the reaction.

Medline reference
van der Werf MJ, Swarts HJ, de Bont JA. Appl Environ Microbiol (1999) 65(5): 2092-102.

Search Medline for 1-hydroxy-2-oxolimonene 1,2-monooxygenase.
1 citations on March 09, 2012.
           (1S,4R)-1-Hydroxy-2-oxolimonene           
                          |
                          |  NADPH + O2
  1-hydroxy-2-oxolimonene | /
        1,2-monooxygenase |/
                1.14.13.- |
                          |\
                   ExPASy | \
                          |  NADP+ + OH-
                          v
 [7-Hydroxy-4-isopropenyl-7-methyl-2-oxo-oxepanone]  
                          |
                          |
                          |
                          |
                          |
                          |
                          |
                          v
         (3R)-3-Isopropenyl-6-oxoheptanoate          
Display a pathway starting from this reaction.

EAWAG-BBD Biotransformation rules in accord with this reaction:
cyclic Ketone -----> cyclic Ester (bt0071)
Lactone -----> Hydroxycarboxylate (bt0024)

[Limonene] [BBD Main Menu]

Page Author(s): Shulan Tian
August 14, 2005 Contact Us

This is the EAWAG-BBD reaction, reacID# r0736.
It was generated on June 16, 2019 7:43:34 AM CDT.

© 2019, EAWAG.