From 2-Oxo-delta3-4,5,5-trimethylcyclopentenylacetyl-CoA to delta2,5-3,4,4-Trimethylpimelyl-CoA

Graphic of the reaction.

Medline reference
Ougham HJ, Taylor DG, Trudgill PW. J Bacteriol (1983) 153(1): 140-52.

Search Medline for 2-oxo-delta 3-4,5,5-trimethylcyclopentenylacetic acid.
2 citations on March 09, 2012.
                                        2-Oxo-delta3-4,5,5-trimethylcyclopentenylacetyl-CoA                                        
                                                                 |
                                                                 |  NADH + H+ + O2
             2-oxo-delta3-4,5,5-trimethylcyclopentenylacetyl-CoA | /
                                               1,2-monooxygenase |/
                                                     1.14.13.160 |
                                                           Kyoto |\
                                                          ExPASy | \
                                                                 |  NAD+ + H2O
                                                                 v
                                   [5-Hydroxy-3,4,4-trimethyl-delta2-pimelyl-CoA-delta-lactone]                                    
                                                                 |
                                                                 |
                                                                 |
                                                                 |
                                                                 |
                                                                 |
                                                                 |
                                                                 v
                                                delta2,5-3,4,4-Trimethylpimelyl-CoA                                                
Display a pathway starting from this reaction.

EAWAG-BBD Biotransformation rules in accord with this reaction:
cyclic Ketone -----> cyclic Ester (bt0071)
5-Hydroxy-3,4,4-trimethyl-delta2-pimelyl-CoA-delta-lactone -----> delta2,5-3,4,4-Trimethylpimelyl-CoA derivative (bt0288)

[(+)-Camphor] [BBD Main Menu]

Page Author(s): Dong Jun Oh
August 14, 2005 Contact Us

This is the EAWAG-BBD reaction, reacID# r0430.
It was generated on September 25, 2017 1:53:25 PM CDT.

© 2017, EAWAG.