From 2,2-Dimethyl-3-pentanone to 1-Hydroxy-4,4-dimethylpentan-3-one

Graphic of the reaction.

Medline reference
Solano-Serena F, Marchal R, Heiss S, Vandecasteele JP. J Appl Microbiol (2004) 97(3): 629-39.

Search Medline titles for isooctane AND degradation AND bacteria.
8 citations on September 10, 2012. 
       2,2-Dimethyl-3-pentanone        
                   |
                   |  O2 + 2H+ + 2e-
        pinacolone | /
   5-monooxygenase |/
          1.14.-.- |
                   |\
            ExPASy | \
                   |  H2O
                   v
  1-Hydroxy-4,4-dimethylpentan-3-one
Display a pathway starting from this reaction.

EAWAG-BBD Biotransformation rules in accord with this reaction:
aliphatic Methyl [H2] -----> primary Alcohol (bt0334)
[Isooctane] [BBD Main Menu]

Page Author(s): Carla Essenberg
May 31, 2006 Contact Us

This is the EAWAG-BBD reaction, reacID# r1279.
It was generated on January 30, 2025 at 6:35:29 AM CST. 

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