The EAWAG-BBD Citronellol Pathway

• Citronellal -----> Citronellate (reacID# r1156)
• Citronellate -----> Citronellyl-CoA (reacID# r1157)
• Citronellol -----> Citronellal (reacID# r1155)
• Citronellyl-CoA -----> cis-Geranyl-CoA (reacID# r1159)
• cis-Geranyl-CoA -----> Isohexenyl-glutaconyl-CoA (reacID# r1166)
• 3-Hydroxy-3-isohexeneylglutaryl-CoA -----> 7-Methyl-3-oxo-6-octenoyl-CoA + Acetate (reacID# r1168)
• 3-Hydroxy-5-methylhex-4-enoyl-CoA -----> 5-Methyl-3-oxo-4-hexenoyl-CoA (reacID# r1305)
• Isohexenyl-glutaconyl-CoA -----> 3-Hydroxy-3-isohexeneylglutaryl-CoA (reacID# r1167)
• 5-Methyl-3-oxo-4-hexenoyl-CoA -----> 3-Methylcrotonyl-CoA (reacID# r1306)
• 7-Methyl-3-oxo-6-octenoyl-CoA -----> 5-Methylhex-4-enoyl-CoA (reacID# r1302)
• 5-Methylhex-4-enoyl-CoA -----> (2E)-5-Methylhexa-2,4-dienoyl-CoA (reacID# r1303)
• (2E)-5-Methylhexa-2,4-dienoyl-CoA -----> 3-Hydroxy-5-methylhex-4-enoyl-CoA (reacID# r1304)

• Acetate [64-19-7] (compID# c0050)
• Citronellal [106-23-0] (compID# c1026)
• Citronellate [502-47-6] (compID# c1029)
• Citronellol [106-22-9] (compID# c1013)
• Citronellyl-CoA (compID# c1031)
• cis-Geranyl-CoA (compID# c1032)
• 3-Hydroxy-3-isohexeneylglutaryl-CoA (compID# c1034)
• 3-Hydroxy-5-methylhex-4-enoyl-CoA (compID# c1138)
• Isohexenyl-glutaconyl-CoA (compID# c1033)
• 5-Methyl-3-oxo-4-hexenoyl-CoA (compID# c1139)
• 7-Methyl-3-oxo-6-octenoyl-CoA (compID# c1035)
• 3-Methylcrotonyl-CoA (compID# c1036)
• 5-Methylhex-4-enoyl-CoA (compID# c1136)
• (2E)-5-Methylhexa-2,4-dienoyl-CoA (compID# c1137)

• EC 1.1.-.- citronellol dehydrogenase (enzymeID# e0717)
• EC 1.1.1.35 3-hydroxyacyl-CoA dehydrogenase (enzymeID# e0664)
• EC 1.2.1.- citronellal dehydrogenase (enzymeID# e0718)
• EC 1.3.1.- citronellyl-CoA dehydrogenase (enzymeID# e0720)
• EC 1.3.99.- enoyl-CoA reductase (enzymeID# e0663)
• EC 2.3.1.9 acetoacetyl-CoA thiolase (enzymeID# e0144)
• EC 4.1.99.- 3-hydroxy-3-isohexenyl-glutaryl-CoA acetate lyase (enzymeID# e0723)
• EC 4.2.1.17 enoyl-CoA hydratase (enzymeID# e0014)
• EC 4.2.1.57 isohexenyl-glutaconyl-CoA hydratase (enzymeID# e0722)
• EC 6.2.1.- citronellyl-CoA ligase (enzymeID# e0719)
• EC 6.4.1.5 geranyl-CoA carboxylase (enzymeID# e0721)

Page Author(s): Dean G. Binger and Michael Turnbull
Sun Feb 19 13:36:09 CST 2006 Contact Us

This is the EAWAG-BBD compounds and reactions page for the Citronellol Pathway.
It was generated on April 17, 2025 at 6:02:16 PM CDT.

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