Rule bt0158

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Pattern 3361        All patterns
Enol ether -> Keto + Alcohol
Aromatic ether -> Aromatic alcohol + Alcohol


Aerobic Likelihood:              Neutral

EAWAG-BBD Reaction(s):
Carbofuran -----> 2-Hydroxy-3-(3-methylpropan-2-ol) benzene-N-methylcarbamate (reacID# r1541)
Carbofuran-7-phenol -----> 3-(2-Hydroxy-2-methylpropyl)benzene-1,2-diol (reacID# r1478)
2-oxepin-2(3H)-ylideneacetyl-CoA -----> 3-Oxo-5,6-dehydrosuberyl-CoA (reacID# r1732)

Comments:
Based on isochorismatase EC 3.3.2.1. Rule will produce cis products in rings with double bonds. If the substrate contains an enol ether, the reaction depicted by this rule produces an enol product. This spontaneously tautomerizes to the keto form, thus the keto form is shown in this rule.

Similarities:
bt0023: dialiphatic Ether --> Alcohol + Aldehyde

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Page Author(s): Bo Kyeng Hou, Rachael Long, Michael Turnbull and Jiun-guo Yu
May 25, 2011

This is the EAWAG-BBD biotransformation rule, ruleID# bt0158.
It was generated on September 19, 2017 6:37:52 AM CDT.

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