From 4-Carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate to 4-Oxalomesaconate

Graphic of the reaction.

Medline reference
Kasai D, Masai E, Miyauchi K, Katayama Y, Fukuda M. J Bacteriol (2005) 187(15): 5067-74.

Search Medline for oxalomesaconate.
9 citations on March 09, 2012.
  4-Carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate   
                            |
                            |  H2O
                      CHMOD | /
                  hydrolase |/
                    3.1.1.- |
                            |\
                     ExPASy | \
                            |  CH3OH + H+
                            v
        [4-Carboxy-2-hydroxyhexa-2,4-dienedioate]        
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                            v
                    4-Oxalomesaconate                    
Display a pathway starting from this reaction.

EAWAG-BBD Biotransformation rules in accord with this reaction:
Ester -----> Alcohol + Carboxylate (bt0024)
Enol -----> Keto (bt0044)

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Page Author(s): Jeanna Danielson
April 18, 2010 Contact Us

This is the EAWAG-BBD reaction, reacID# r1640.
It was generated on January 17, 2019 7:04:21 AM CST.

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