From 2,2-Dimethyl-3-pentanone to 1-Hydroxy-4,4-dimethylpentan-3-one

Graphic of the reaction.

Medline reference
Solano-Serena F, Marchal R, Heiss S, Vandecasteele JP. J Appl Microbiol (2004) 97(3): 629-39.

Search Medline titles for isooctane AND degradation AND bacteria.
8 citations on September 10, 2012.
       2,2-Dimethyl-3-pentanone        
                   |
                   |  O2 + 2H+ + 2e-
        pinacolone | /
   5-monooxygenase |/
          1.14.-.- |
                   |\
            ExPASy | \
                   |  H2O
                   v
  1-Hydroxy-4,4-dimethylpentan-3-one   
Display a pathway starting from this reaction.

EAWAG-BBD Biotransformation rules in accord with this reaction:
aliphatic Methyl [H2] -----> primary Alcohol (bt0334)

[Isooctane] [BBD Main Menu]

Page Author(s): Carla Essenberg
May 31, 2006 Contact Us

This is the EAWAG-BBD reaction, reacID# r1279.
It was generated on June 18, 2019 10:50:06 PM CDT.

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