From 2,4-Dihydroxylamino-6-nitrotoluene to 2-Amino-5-hydroxyl-4-hydroxylamino-6-nitrotoluene

Graphic of the reaction.
Reference: Hughes, J. B., Wang, C., Yesland, K., Richardson, A., Bhadra, R., Bennett, G., & Rudolph, F. (1998). Environmental Science and Technology, 32, 494-500.
Search Medline for bamberger rearrangement.: 16 citations on March 09, 2012.

          2,4-Dihydroxylamino-6-nitrotoluene          
                           |
                           |  H⁺ + e^-
                           | /
                           |/
                           |
                           v
                           |
                           |
                           v
  2-Amino-5-hydroxyl-4-hydroxylamino-6-nitrotoluene

Display a pathway starting from this reaction.

EAWAG-BBD Biotransformation rules in accord with this reaction:: aromatic Hydroxylamine -----> aromatic Amine (bt0035); monosubstituted Benzenoid -----> Add m-OH (bt0012)

[2,4,6-Trinitrotoluene (anaerobic)] [BBD Main Menu]

Page Author(s): Guang Yao
August 14, 2005 Contact Us

This is the EAWAG-BBD reaction, reacID# r0628.
It was generated on April 19, 2024 at 8:24:15 AM CDT.

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