From 6-Oxo-2-hydroxy-7-(4'-chlorophenyl)-3,8,8-trichloroocta-2Z,4Z,7-trienoate to 2-(4'-Chlorophenyl)-3,3-dichloropropenoate and cis-2-Hydroxy-3-chloropenta-2,4-dienone

Graphic of the reaction.

Medline reference
Hay AG, Focht DD. Appl Environ Microbiol (1998) 64(6): 2141-6.

Search Medline for bacteria AND DDT AND DDE.
35 citations on March 09, 2012.
                                        6-Oxo-2-hydroxy-7-(4'-chlorophenyl)-3,8,8-trichloroocta-2Z,4Z,7-trienoate                                        
                                                                            |
                                                                            |  H2O
  6-oxo-2-hydroxy-7-(4'-chlorophenyl)-3,8,8-trichloroocta-2E,4E,7-trienoate | /
                                                                  hydrolase |/
                                                                    3.7.1.- |
                                                                            |\
                                                                     ExPASy | \
                                                                            |  H+
                                                                            v
                                  2-(4'-Chlorophenyl)-3,3-dichloropropenoate + cis-2-Hydroxy-3-chloropenta-2,4-dienone                                   
Display a pathway starting from this reaction.

EAWAG-BBD Biotransformation rules in accord with this reaction:
1-Aldo/keto-2,4-diene-5-ol -----> Carboxylate + 1-ene-4-one (bt0040)

[1,1,1-Trichloro-2,2-bis-(4'-chlorophenyl)ethane (DDT)] [BBD Main Menu]

Page Author(s): Jingfeng Feng
August 14, 2005 Contact Us

This is the EAWAG-BBD reaction, reacID# r0444.
It was generated on September 22, 2019 9:52:41 PM CDT.

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